Alteration

An IOCG deposit is a giant, intense area of  metasomatic alteration in both breadth and height, and following will illustrate some of the alteration types on the Molly Marie Prospect.

Three main areas have been created in the photo below to aid in describing the types alteration that exist on the prospect (it is known now, that silica mounds are present on top of the basalt between all of the areas):

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Areas of the Molly Marie Claim Group

Area 1

This area is comprised of massive phreatic arkose breccias on the western perimeter of the collapse caldera, the basalt, which once overlaid the breccia, has been  absorbed by the breccia below and/or eroded away.   The breccias are what was the Whitetail formation that is approximately 500 feet thick.  The alteration here is textbook, grading from epidote on the perimeter, to sericite, chlorite and silication of the marble cobbles in the center of the area.  The zones overlap, and silicification overprints all of them.

Area 2

Portions of this area were mined previously as described in the “Great Mine” page.  The deposit formed alongside the Rhyolite neck of the  strata volcano and there are hydrothermal silica mounds covering much of the area. There are large outcrops of hematite breccia found on the hill dubbed “Cerro Negra”, which is a large silica/hematite mound .  There is very strong magnetism in the silica in the area.

Area 3

This area has a maar diatreme on the northern end and three large hydrothermal silica mounds.  The geology here is more complicated due to multiple explosive events,  and there is intense magnetism of near and on the mounds in this area, and  intense calcification, silication, and types of gossans not seen in the other 2 areas.

General

Most ore outcrops have been removed from the arkosic breccias of the claim group by hand-dug pits, but the alteration that surrounds the former outcrops remains.  On a district scale, iron alteration can be seen from Google Earth, and on the ground, other forms of district-scale alteration can be found.  The following are descriptions of the types of alteration can be found at the Molly Marie Prospect, starting generally from the outside of the areas working inward:

Albite – Magnetite Alteration

There is a zone of strongly magnetic granite approximately 400-500 yards wide that surrounds the caldera.  Details of magnetite alteration are on the Magnetism and Iron Oxides page.

Clay or Argillic Alteration

The discovery that the Molly Marie Prospect was located on a collapse caldera occurred after enhancing a Google Earth photo.  The iron stained “halo” over one mile in diameter can be seen below, with the west side breccias having the most clay and iron alteration.  The iron gives the red coloration to the great amount of clay overlying much of Area 1 and especially the east sides of the ridges; all of the red clay is saturated with magnetite.   Typically, the float and outcrops of breccia in the clay-covered areas are laced with drusy quartz, further evidence of extensive boiling that occurred below.  On the right side of the photo, remnants of the slope of the strato-volcano can be seen.  The volcano’s neck is on the south side of the caldera and is located just north of the First Water trailer parking lot; it is a pink color in the photo.

The Tertiary brine lake was located on the western side of the collapse caldera, and on the western side is where most of the brecciation occurred.  This is believed to have been the “wet side” and and is also where the likely bulk of the ore formation took place.

Clay + Iron Alteration (The Halo)

Typically, the alteration zones are more exposed on the west side of Area 1 because of less red clay cover, and because the Chlorite zone is largely covered by basalt on the east side of the ridges.

Syenite Alteration

There are large areas outside of the caldera where the pegmatitic Ruin granite has been altered to Syenite, as named and drawn by Napoleon’s geologist in Syene, Egypt .  One dike of this rock can be found cutting basalt in the interior of the Molly Marie caldera. The Syenite occurs in the perimeter of at least 3 of the local calderas.  An outcrop on the periphery of the Molly Marie caldera is below.

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Syenite outcrop

This is what the Syenite looks like when sawn.

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Syenite sawn

This is what the Syenite looks like where it is exposed in a wash and water-worn.

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Syenite after Ruin Granite

Shown in the photo below is  a zone on the margin of the Molly Marie Caldera, and it is believed that this is the same Syenite as above, but heat drove the orthoclase off  the Syenite in second pulse of heat leaving only the orthoclase as shown below.

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Kspar

Epidote Alteration

The epidote alteration on the claim group on western and southern sides of ridges of Area 1 is intense and widespread, and indicates just how large this hydrothermal system is.  The photos below are un-enhanced.

Epidote Alteration
Massive epidote alteration

Sericite Alteration

The west and east sides of Area 1 have a very wide zone of Sericite alteration.  An example of the Sericite Phyllite that is found extensively on Area 1 ridges is shown below:

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Sericite Phyllite

Below is a photo of an  outcrop of Sericite Phyllite on the western side of the Area 1:

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Sericite Phyllite Zone on the West side of the Brecciated Ridges

Below is another outcrop of the Sericite Phyllite.

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More Sericite Phyllite

Phyllic Alteration

Along most of the the eastern side of the ridges in Area 1 there is a an large intense outcropping of foliated quartz as shown below,   It is known now that these are likely feeders for silica mounds located on fault zones.

http://mollymarieprospect.com/outcropphotos/Sercteoutcrp.JPG
Phyllic Alteration Zone on the East Side of the Area 1

Below is a closeup photo of the foliated quartz on the east side of Area 1.  It is suspected that there is supergene ore beneath this zone at a shallow depth.

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Phyllic Alteration and Foliated Quartz

Black  and Green Chlorite Alteration

Of all the alteration types found on the Prospect, black Chlorite (high iron) alteration is one of the most pervasive, and can be found in bottom of many of the gulches and hilltops in the brecciated areas.   The Chlorite alteration replaces feldspar, and occurs in abundance in Area 1 in the breccias.  The areas where the seismic surveys have been done, and quartz outcrops, align well with Black Chlorite outcrops on their perimeters, and the Black Chlorite indicates where many more untested potential pits are located.

Black Chlorite Alteration

Four 50-foot core holes were drilled in the breccias, and extensive black chlorite alteration of the feldspar was prevalent in two of them.

Black Chlorite Alteration in Core

Another photo of  Black Chlorite alteration is shown below, gathered about a hundred feet from the Needle Overlook park bench at the end of the sidewalk:

Select Black Chlorite alteration

Below is a close-up of green chlorite alteration found extensively in some brecciated areas; the boulders and cobbles of granite in the upper Whitetail formation are more susceptible to alteration. The green chlorite and greenstone are found in a wide zones  in Area 1, and it has been generally been found found where the IOCG vents and quartz outcrops are located.

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Chlorite

Greenstone, another form of chlorite alteration,  is also found scattered on the hillsides:

Greenstone

Although not shown, Much basalt is also heavily chloritized.

There has been much recent erosion due to heavy rains after an extended drought, and more of the choritized arkose in the Area 1 breccias has been exposed as in the photo below.

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Chloritized Arkose

Below is breccia that is chloritized and has an epidote veinlet running through it.

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Epidote Veinlet

Apatite Alteration

In Area 2, on and near Cerro Negra, the Apatite alteration is most obvious.  It is the classic Apatite blue, but the brown blotches are suspected to be apatite also.  What is suspected to be abundant waxy yellow apatite is found in Area 1 in breccias in the basalt and in an large exposure of iron oxide. Below is a photo of pieces of the blue variety of apatite with suspected brown also found near Cerro Negra.

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Apatite alteration

Some of the basalt in all areas is a light blue and it was tested using the phosphate test using nitric acid ammonium molybdate.  A yellow precipitate is formed if there is phosphate (Apatite).  Although many rocks have some phosphate in them, when left for 24 hours, this test can be semi-quantitative.

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Results of a positive Phosphate test

Marble

The chlorite zone in the brecciated Whitetail formation of Area 1 has an abundance of limestone cobbles and boulders that have been metamorphosed into Marble.  Below is a photo of a cobble from at first appearance is a limestone cobble, but one hit with a hammer reveals that it is red marble.  Note the conchoidal flake of marble on the right.

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A filled-in pit proven by seismic methods is nearby the boulder of pink marble shown below. On the breccia ridges, most of the limestone cobbles have been altered to red, gray, or banded marble, some ring like glass when struck with a  hammer.

Marble

Silication

Although not normally as dense as shown below, the unaltered brecciated Whitetail formation has an abundance of limestone and marble cobbles.

http://mollymarieprospect.com/sitephotoslatest/marble3.jpg

The hilltop area in the photograph below has no limestone cobbles, as they have been replaced by silica, either jasperoid, saccharoidal silica, or sponge silica. There is likely a boiling zone beneath this area.  The Needle Overlook parking lot is in the center of this photo.

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Below is a piece of limestone with fossils that has been replaced by silica, creating a “sponge” texture.

Limpet and other fossils in Carbonate replaced by Silica Sponge

Below is a cobble of limestone that has been nearly replaced by saccharoidal silica:

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Saccharoidal Silica Replacement of Limestone

More limestone replaced by silica, creating a sponge texture:

Fossil Snail replaced by Silica Sponge

The below fossilized barnacle and microbial mat (right side)  were encased in saccharoidal silica in shallow water at the same time as the ore was being formed.

Fossil Barnacle and Microbial mat in Saccharoidal silica

The picture below is of a typical pebble of limestone that has been replaced by silica.  A buoyancy test was performed on this rock, and it nearly floats. By zooming in, it can be seen just how porous and fossiliferous this pebble is.

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Silica Sponge

 

Jarosite Alteration

Below is a photo of the Silica with Jarosite alteration that the vent mounds shown on the exhalites page are comprised of.  This is highly magnetic material.

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 Silica with Jarosite alteration

Below is a photo of the Jarosite altered material.  Cubes of Jarosite can be seen with a 20x loupe that were the original pyrite.

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Jarosite Alteration

In some locations on the Silica-Jarosite vent mounds,  narrow dikes of what is assumed to be rhyolite cuts the layers of silica.

Rhyolite dikelets

Silicification and Drusy Quartz

Most of the breccia zones in Area 1 are heavily inundated with drusy quartz.

The hematite breccias that are the vent of the IOCG beneath the hill dubbed “Cerro Negra”  in Area 2 are surrounded by basalt, and they are surrounded by a zone of silicification  as shown in the photo below. Some of this material is highly florescent under UV light (red). This basalt is highly magnetic, a result of  metasomatism, which was caused by mineralized fluids boiling beneath the basalt.

Silicified basalt

The outcrop in the photo below was thought to be silicified basalt, but it is now known now to be a silica deposit that is a highly magnetic material and has a “knobby texture” that is different that than most of the silica mounds:

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Highly magnetic silica

Hematite Alteration

This sawn rock below was thought to be hematite altered basalt, because of the large clasts in the rock. It is known now to be silica/hematite from one of the smaller mounds. In the vugs Actinolite can be seen.

Silica/Hematite from one of the smaller mounds.

Below is a photo of a sawn piece of another type of silica that was either secondary silicification after the silica mound was formed, or a deposition band.  The veinlet of quartz is about 1/2 mm wide. What appear to be voids lined with hematite is clear quartz.  This material is highly magnetic also and magnetite can be seen.

Silicified Basalt

Silicification and drusy quartz is found throughout all alteration zones in the brecciated arkose.

Below is a piece of arkose breccia that is common in outcrops in Area 1, and quartz crystals lining the voids can be seen.  Under magnification, the full extent of drusy quartz is visible.  Some brecciated arkose  areas have been completely replaced by silica and only faint outlines of the clasts remain.

Silicification, Drusy Quartz

Some silica mounds on the basalt between Areas 1 and 3 are saturated with banded quartz veinlets.   It is believed to be from a secondary silicification event.

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Quartz Veinlets in Basalt

Below is a piece of veinlet material that was cut and polished:

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Banded Maricunga-style Veinlet

Metabasalt and Amphibolite

On the ridges in Area 1 can be found patches of amphibolite fragments that are nearly 100% hornblende.  During ore formation, the basalt that overlaid the Whitetail arkose was fragmented by brecciation, but could have been buried under as much as 2000 feet of volcanic debris.  It is assumed that the basalt above the boiling zones was transformed to Amphibolite.   Below are some of the larger pieces found.

Amphibolite

Vuggy Silica

On the southern perimeter of the collapse caldera in Area are found breccias consisting of mostly Vuggy Silica.  This piece below came from a shallow prospect pit on the southern edge of Area 1.

Vuggy Silica breccia

Hematite Alteration

Rather than alteration, it is known now that the hematite is typically found internally in the silica mounds.  There are at least 2 separate areas in Areas 2 and 3  that have large outcrops of milled hematite breccia, some of it containing noticeable apatite when a fresh face is magnified.

Hematite Breccia Outcrop

Calcification

Near the Cerro Negra in Area 2 and other places on the Molly Marie Prospect, many calcite veins are found that exhibit red fluorescence under short wave UV light.  Some of it is shown below.  Some basalt on the property glows like charcoal briquettes at night under UV.  In the famous zinc mines of Franklin, New Jersey, core was “lamped” with UV to look for red calcite.  If red calcite was “lamped”  it was known that a zinc orebody was nearby.  It is believed the same phenomena is present at the Molly Marie Prospect. It is known now that the calcite veins are located at prior vents.

Below is a photo of some pieces of calcite-quartz veins found in abundance in some areas:

Calcite Vein Material in Normal Light

Below is the same calcite under UV light:

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Calcite under short-wave UV

Near the maar diatreme in Area 3, there is a large outcrop of breccia that is comprised of rounded fragments of mafic magma and is exposed for approximately 200 feet in a wash . The matrix is milled arkosic material that is inundated with Apatite? when magnified.  A photo of the breccia is below.

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Milled Breccia

One of the rounded fragments is shown below after it is sawn.  The dark portion in the center is where dilute HCl was applied.  The pencil lead is .7mm.  The sawn face of this cobble literally glistens in the sunlight due to calcification.  This mafic material appears to have cooled very quickly.

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Calcified cobble

Advanced Argillic Alteration

Large portions of basalt in Area 2 have been altered to a red clay by acid alteration?.  Some of these areas are inundated with quartz veinlets.  Some of these altered basalt areas can be seen with Google Earth.  This material is highly magnetic.  It is suspected now that this is the hematite material is not advanced argillic alteration but is what remains after the silica is eroded away in some of the mounds.

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Advanced Argillic Alteration of Basalt

After recent erosion, some quartzite cobbles of the Whitetail formation have been exposed that have been exposed to hematite replacement? as in the photo below.

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Acid destruction of Quartzite

Arkose breccia in Area 1 that is incised by washes has intense advanced argillic alteration including resultant kaolinite and alunite .

http://mollymarieprospect.com/sitephotoslater/advargillic.JPG
Advanced Argillic Alteration of Arkose

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