All gossan outcrops have been removed from the arkosic breccias of the claim group, but the localized alteration that surrounds the former outcrops remains.  On a district scale, the iron alteration can be seen from Google Earth, and on the ground, other forms of district-scale alteration can be found.  The following types of alteration can be found at the Molly Marie Prospect:

Clay Alteration

The discovery that the Molly Marie Prospect was located on a collapse caldera above a magma chamber occurred after enhancing a Google Earth photo.  The iron stained “halo” over one mile in diameter can be seen below, with the west side breccias having the most exposed iron and clay alteration.  Of all metals, the brine had the most affinity for iron, which was dissolved from the volcanic strata above. The iron masks the great amount of clay alteration that took place in the brecciated areas, and the slopes of the brecciated areas are covered by a thick layer of red clay.  Typically, the float and outcrops of breccia in the clay covered areas are inundated by drusy quartz, further proof that extensive boiling occurred below.  On the right side of the photo below, remnants of the slopes of the strato-volcano can be seen.  The volcano’s neck is just north of the First Water trailer parking lot.

The brine lake was on the western side of the collapse caldera, and on that side it is why it is suspected that most of the breccias occur there and why the bulk of the ore formation took place.

Clay + Iron Alteration (The Halo)

Black Chlorite Alteration

Of all the alteration types found on the Prospect, Black Chlorite alteration is the most important regarding VMS deposits.  Black Chlorite alteration is exclusive to VMS deposits, and besides exhalites, is the number one thing to look for when exploring for them.  Black Chlorite alteration replaces feldspar, occurs in the phreatic arkose breccias on the west side of the Prospect, and can be seen on the walls of the washes in exposed  breccia rock.  The seismic surveys that have been done align well with Black Chlorite outcrops, and the Black Chlorite indicates where many more several more untested potential pits are located.

Black Chlorite Alteration

Four 50-foot core holes were drilled in the breccias, and extensive black chlorite alteration of the feldspar was prevalent in two of them.

Black Chlorite Alteration in Core

Because of the importance of the Black Chlorite and its importance in solving the puzzle, another photo of  Black Chlorite alteration is shown below, gathered about a hundred feet from the Needle Overlook bench at the end of the sidewalk:

Select Black Chlorite alteration

Below is a close-up of green chlorite alteration found extensively in some brecciated areas, as selectively alters granite boulders and cobbles more than others.

Granitic rock in some of the arkose breccias is very susceptible to green chlorite alteration as shown below.


Silicification and Drusy Quartz

The gossans that are present on the hill dubbed “Cerro Negra” by the author do not have Black Chlorite surrounding them because they are surrounded by basalt, but they are surrounded by a zone of silicification  as in the photo below. Some of this material is highly florescent under UV light (red).

In some areas, the basalt has been nearly completely replaced by silica through the process of metasomatism, and the augite has been replaced by epidote.  It is speculated that the Whitetail formation below the basalt in these areas has been replaced by massive vuggy silica.

Below is a photo of sawn piece of another type of silicified basalt.  The veinlet of quartz is about 1/2 mm wide. What appear to be voids are augite replaced with clear quartz.

Silicified Basalt

Below is a piece of phreatic arkose breccia that is common in outcrops, and quartz crystals lining the voids can be seen.  Under magnification, the full extent of drusy quartz is visible.  Some arkose breccia areas have been completely replaced by silica and only faint outlines of the clasts remain.

Silicification, Drusy Quartz

Below are photos of cobbles of carbonate with fossils from the ridges of breccia that have been replaced by a very light spongy silica.  This is more evidence of boiling zones below.

Limpet and other fossils in Carbonate replaced by Silica Sponge
Fossil Snail replaced by Silica Sponge

It is reasoned that the below fossil barnacle and microbial mat (right side) were encased in granular silica in shallow water at the same time the ore was being formed .

Barnacle and Microbial mat on granular silica

Some areas in the basalt are saturated with quartz veinlets.  It is believed that a VMS below is closely associated with these veinlets.

Epidote Alteration

The epidote alteration on the claim group on the western side of the breccia ridges  is intense and widespread, and indicates just how large this hydrothermal system is.  The photos below are un-enhanced.

Epidote Alteration
Massive epidote alteration

The east side of the arkose breccia ridges has an intense phyllic alteration zone.  it is believed that this is associated with VMS deposits in the breccias to the west.  This type of alteration has been reported for rock surrounding VMS deposits in South America.
Phyllic-altered arkose breccia


The upper portion of the Whitetail formation is laden with marble and limestone cobbles, sand and boulders, but below is a strange occurrence of marble that appears to be an intact bed.  A filled-in pit proven by seismic methods is nearby.  On the ridges, much of the limestone cobbles have been altered to marble, some ringing like glass when struck with a  hammer.  The marble cobbles and boulders is synonymous to a “marble front” found near sulfide replacement deposits; another indication of the boiling zone below.


Metabasalt and Amphibolite

On the breccia-ridges can be found patches of amphibolite fragments that are 100% hornblende.  During ore formation, the basalt that overlaid the Whitetail arkose was fragmented by the brecciation, but was buried under at much as 2000 feet of volcanic debris.  The basalt above the boiling zones was transformed to Amphibolite by superheated steam.   Most of the Amphibolite that remains is in small pieces and takes a trained eye to recognize.  Below are some of the larger pieces found.


Basalt Hornfels

Areas  of basalt that are underlain by rhyolite are “cooked” to a laminated rock that is a nondescript brown color.   In the photo below, this rock can be seen, with dikelets of intrusive rhyolite breccia that betray the rocks origin.

Basalt Hornfels

Vuggy Silica

As written in the Ore Genesis page,  it is theorized that massive Vuggy Silica was created above the magma chamber during the “dry phase”.  On the southern perimeter of the collapse caldera is found breccias consisting of mostly Vuggy Silica.  This piece below came from a shallow prospect pit on the southern edge of the collapse caldera.

Vuggy Silica breccia

Sulfide Replacement

The massive gossan breccia outcrops at the hill dubbed “Cerro Negra” appear to indicate that there was 100% replacement of the Whitetail formation beneath the basalt.  Whether this is due to the high amounts of limestone and marble in the Whitetail or the intensity of the boiling is not known; maybe due to both.  There are at least 3 separate VMS deposits in the basalt area  that have large outcrops of milled gossan breccia, some of it containing noticeable Aurichalcite when a fresh face is magnified.

Gossan Outcrop

Activated Calcification

Near the Cerro Negra VMS and other places on the Molly Marie Prospect, many calcite veins are found that exhibit red fluorescence under short wave UV light.  Some basalt on the property glows like a giant barbecue briquette under UV.  In the famous zinc mines of Franklin, New Jersey, core was “lamped” with UV to look for red calcite.  If red was found it was known a zinc orebody was nearby.  It is believed the same phenomena is present at the Molly Marie.
Calcite under short-wave UV